LOCTITE ECCOBOND LCM 1000AG-1


Main features
  • High Toughness
  • Ultra Low warpage
  • CTE matching Silica

Product Description

LOCTITE ECCOBOND LCM 1000AG-1 is an epoxy amine based system, used in liquid compression molding and with low stress, exhibiting ultra-low-warpage during wafer-level process, and showing excellent chemical resistance and thermal stability properties. It is a non anhydride, SVHC free encapsulant for wafer level encapsulation.

LOCTITE ECCOBOND LCM 1000AG-1 is a black liquid paste with high purity that is typically used on wafer level packaging and high density (less than 100um die to die) Fan Out applications. Instead of encapsulating the chip post dicing, you encapsulate the entire wafer and dice it afterwards.

LOCTITE ECCOBOND LCM 1000AG-1 presents a breakthrough encapsulation material that leverages a unique anhydride-free resin platform to enable thorough protection, improved warpage control and fine gap filling for chip-on-wafer (CoW) encapsulation.

LOCTITE ECCOBOND LCM 1000AG-1 is a solvent-free encapsulant that integrates exceptionally fine particle fillers (average 3 µm, upper cut 10 µm), enabling high-yield, ultra-low warpage, excellent flow properties for void-free fine-dimension filling, and fast in-mold cure times for improved UPH. In testing, LOCTITE ECCOBOND LCM 1000AG-1 exhibited the following performance benefits:

  • Ultra-low Warpage of – When evaluated on an 8” wafer, Henkel’s LCM resulted in extremely low wafer warpage of 0.39 mm after post-mold curing.
  • Void-free Fine Gap Filling – Formulated with finer particles, LOCTITE ECCOBOND LCM 1000AG-1 quickly penetrates narrow trenches between die (FI WLP process), and is able to fill a 40 µm x 400 µm trench with no voids.
  • High Throughput – Lab evaluation confirmed the material’s high throughput capability, with the Henkel LCM achieving an in-mold cure time of five minutes.

 

Product Family
LCM1000AG-1  
Cartridge

Catalog Product

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Technical Specifications

General Properties
Filler Content 84 %
Specific Gravity
Specific Gravity
Specific gravity (SG) is the ratio of the density of a substance to the density of a reference substance; equivalently, it is the ratio of the mass of a substance to the mass of a reference substance for the same given volume.

For liquids, the reference substance is almost always water (1), while for gases, it is air (1.18) at room temperature. Specific gravity is unitless.
1.92
Physical Properties
Thixotropic index
Thixotropic index
Thixotropic Index is a ratio of a material s viscosity at two different speeds in Ambient temperature, generally different by a factor of ten.

A thixotropic material s viscosity will decrease as agitation or pressure is increased. It indicates the capability of a material to hold its shape. Mayonnaise is a great example of this. It holds its shape very well, but when a shear stress is applied, the material easily spreads.

It helps in choosing a material in accordance to the application, dispense method and viscosity of a material.
1.7
Viscosity
Viscosity
Viscosity is a measurement of a fluid’s resistance to flow.

Viscosity is commonly measured in centiPoise (cP). One cP is defined as
the viscosity of water and all other viscosities are derived from this base. MPa is another common unit with a 1:1 conversion to cP.

A product like honey would have a much higher viscosity -around 10,000 cPs-
compared to water. As a result, honey would flow much slower out of a tipped glass than
water would.

The viscosity of a material can be decreased with an increase in temperature in
order to better suit an application
800,000 mPa.s
Chemical Properties
Ionic Content
Chloride (Cl-)
Chloride (Cl-)
The amount of Chloride (Cl-) ion extracted from the product in parts per million (ppm)
1.5 ppm
Potassium (K+)
Potassium (K+)
The amount of Potassium (K+) ion extracted from the product in parts per million (ppm)
0.1 ppm
Sodium (Na+)
Sodium (Na+)
The amount of Sodium (Na+) ion extracted from the product in parts per million (ppm)
0.3 ppm
Mechanical Properties
Storage (DMA) Modulus
Storage (DMA) Modulus @ 25°C 19,000 N/mm2
Thermal Properties
Coefficient of Thermal Expansion (CTE)
Coefficient of Thermal Expansion (CTE)
CTE (Coefficient of thermal expansion) is a material property that is indicative of the extent to which a material expands with a change in temperature. This can be a change in length, area or volume, depending on the material.

Knowing the CTE of the layers is helpful in analyzing stresses that might occur when a
system consists of an adhesive plus some other solid component.
Coefficient of Thermal Expansion (CTE), α1
Coefficient of Thermal Expansion (CTE), α1
CTE α1 (alpha 1) is the slope of the Coefficient of thermal expansion in a temperature range below the Glass transition temperature (Tg).

It explains how much a material will expand until it reaches Tg.
8 ppm/°C
Coefficient of Thermal Expansion (CTE), α2
Coefficient of Thermal Expansion (CTE), α2
CTE α2 (alpha 2) is the slope of the Coefficient of thermal expansion in a temperature range above the Glass transition temperature (Tg).

It explains the extent to which a material will expand after it passes Tg.
18 ppm/°C
Glass Transition Temperature (Tg)
Glass Transition Temperature (Tg)
The glass transition temperature for organic adhesives is a temperature region where the polymers change from glassy and brittle to soft and rubbery. Increasing the temperature further continues the softening process as the viscosity drops too. Temperatures between the glass transition temperature and below the decomposition point of the adhesive are the best region for bonding.

The glass-transition temperature Tg of a material characterizes the range of temperatures over which this glass transition occurs.
135 °C

Additional Information

LCM1000AG-1 Additional Technical Specifications

LCM1000AG-1Additional Tech Specifications

In the semiconductor market, where some argue that Moore’s Law is reaching its limit, the drive to implement extraordinary increases in functionality while diminishing – or maintaining – device dimensions is unabated.  In order to achieve the desired footprints alongside cost/performance objectives, chip integration and new packaging approaches to functionality expansion are required.   Fan-In Wafer-Level Packaging (FI WLP) and Fan-Out Wafer-Level Packaging (FO WLP) are two approaches that are showing promising cost efficiency and performance benefits as indicated by their market growth.  According to market analyst, Yole Development, the CAGR from 2016 – 2022 for FO WLP is 31%, while FI WLP is projected to see 8% growth in the same period.  For applications like data processors, mobile devices and automotive industrial systems, advancement of these technologies is good news.  FO WLP is an extension of standard wafer-level packaging (WLP), but one that enables more I/O connections without having to increase the die size, allowing for a smaller package footprint with improved thermal and electrical performance.  The process flow for FO WLP as compared to traditional WLP, where integrated circuits are packaged while they are still part of the wafer, is different.  In FO WLP processing, the wafer is diced first and the dies are then placed onto a carrier, which is then compression molded.  A redistribution layer is made on top of the entire molded area, following which solder balls are mounted onto the top. 

Fan out WLP Process Flow

Figure 1:  FO WLP process flow (chip-first, die face-down).  

Alternatively, FI WLP is a technology in which an integrated circuit is packaged at the wafer level as  opposed to the fan-out approach of assembling various dies into a package after wafer dicing.  The FI WLP  approach is suitable for packaging dies with low input-output (I/O) counts. With this technique, a redistribution layer is used to connect copper pillars or bumps/balls on top of the die surface. Trenches are cut in between the individual dies, then filled with molding material to offer device protection prior to grinding and dicing into single units.

FI WLP Process Flow

Figure 2:  FI WLP process flow.  

The Role and Evolution of Liquid Compression Molding for WLP Technology 

For both technologies, molding or encapsulation materials are essential, but serve different purposes.  In the case of FO WLP, the compression molding step is where liquid molding materials are used to coat the dies on the reconstituted wafer.  The encapsulating material –or liquid compression molding (LCM) material -- is critical for both handling to enable subsequent process steps and also to protect against warpage.  With thinner dies – some as thin as 50 µm– the risk of warpage and, therefore, damage is large.   LCM materials help reduce or eliminate that risk.  For FI WLP devices, five- or six-side protection of the dies is necessary.  This is achieved by filling the cut trenches with molding material to encapsulate all four sides and the die top with protective material prior to singulation. This protective layer prevents processing damage and enhances reliability during assembly. Until recently, the LCM materials widely available on the market were very granular or powder-type materials with large fillers (25 µm – 50 µm upper cut) built on anhydride resin platforms.  In many cases, the materials resulted in high wafer warpage after molding which may ultimately lead to downstream wafer handling issues.  Ideally, warpage should be kept to < 1 mm throughout the process.  Secondly, the larger filler sizes of the granular LCMs prevent effective coverage and penetration between dies.  The high-density nature of FI WLP and FO WLP technology makes the use of larger filler packages problematic.  In order for materials to provide thorough encapsulation, fine fillers (average size 3 µm, with upper cuts at 10 µm) are desirable.  Finally, while anhydride chemistry is effective, certain anhydrides are banned under the guidelines of the EU REACH legislation, identifying them as substances of very high concern (SVHCs) that could potentially be a supply chain risk if used in LCM formulations.  With these realities as the backdrop, a team of chemistry specialists began the development of a new line of encapsulants that would overcome current challenges for liquid compression molding processes and enable higher reliability FO WLP and FI WLP devices.  The result is a novel LCM formulation, LOCTITE ECCOBOND LCM 1000AG-1, built on a REACH-compliant, anhydride-free resin platform which has led to improved properties as they relate to warpage control, gap filling and in-mold curing.  The material can be used for both FI WLPs and FO WLPs according to the process flows shown in Figures 1 and 2 above.  Henkel’s new anhydride-free platform has shown significant improvements in:

Warpage Control 

Warpage comparison LCM1000-AG1

After curing, an 8” wafer coated with the Henkel LCM showed < 1.0 mm warpage versus 2.6 mm warpage with the anhydride LCM material.  The platform can be modified for different applications, while maintaining ultra-low warpage control.  

Fine Gap Filling

Fine gap filling LCM1000-AG1

Because of the fine filler particles used in the new Henkel LCM, fast flow rates and void-free trench filling and underfilling is achieved, leading to more complete coverage, protection and long-term reliability. A trench measuring 40 µm in width by 400 µm in depth is completely filled with no voids using the next generation LCM material.  

High Throughput Process 

With a five-minute in-mold cure time versus an average ten-minute cure time for anhydride-based LCM  encapsulants, the Henkel’s LOCTITE ECCOBOND LCM 1000AG-1 material allows advanced packaging specialists to more than double throughput and accelerate UPH. 

LCM1000-AG1 throughput improvement

Figure 3:  Henkel’s LCM material significantly improves throughput.  

As FO WLP and FI WLP devices are increasingly incorporated into electronic systems to satisfy  footprint/cost/performance expectations, materials like Henkel’s latest LCM innovation will be required to ensure reliability and enduring function. To learn more, visit Henkel Adhesives or contact us

Recommended Cure Schedule

  • 10 min @120°C (In mold cure)
  • 1 hour @150°C (Post mold cure) 

 

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