Light Emitting Diodes

Light Emitting Diodes

Lightning, Biological and Indicators

Transceivers, Receivers, Emitters

Light Emitting Diodes

Light emitting diodes are light emitting dies that get their color or hue through the phosphor that is coated on top of the die. They are typically blue tinted and are getting their color from a combination of the phosphor, the die light intensity and the overmolded optoelectronic molding compound. There are multiple LED types for a huge variety of applications, ranging from simple through hole monochrome LEDs to backlight, organic, miniLEDs and industrial baylights. All of these LED types have the same principle but completely different application and reliability requirements.

Light emitting diodes generate light upon the absorption of electrical energy. include a multitude of technologies and devices that utilize the interaction between light and materials. To maximize light generation and emission, LEDs are designed to minimize reflection at material interfaces and are encapsulated with materials that allow light transmission while protecting the LED.

 

Target Applications for Next-Generation LED Materials

  • UV LEDs for applications below 300 nm, where transmission is challenging

  • Mid- to high-power LEDs with junction temperatures exceeding 150 °C, requiring UV-resistant materials due to epoxy and silicone degradation.

  • Outdoor RGB SMD LED applications that require UV resist

  • UV and  visible light reflectors with excellent temperature resistance and color stability, particularly in white



applicationofLEDs

 

How can a diode produce light?

Diodes produce light through a process called electroluminescence. When an electron in a diode moves from a higher energy state to a lower one, it releases energy in the form of a photon. This energy can be visible as light if the diode is made of a material that allows for the emission of photons within the visible spectrum.

As discussed in diode application, free electrons can fall into empty holes from the P-type layer. This transition from a higher energy level to a lower one results in the emission of a photon. However, the specific frequency and energy of the emitted photon depend on the material used in the diode.

Standard silicon diodes, for instance, emit photons in the infrared range. This means the light they produce is invisible to the human eye. However, other materials, like gallium arsenide phosphide, can be used to create diodes that emit photons in the visible spectrum, producing visible light. These diodes are commonly used in LEDs (Light-Emitting Diodes) for various applications, including lighting, displays, and communications.

The main semiconductor materials used to manufacture LEDs are:

  • Indium gallium nitride (InGaN): blue, green and ultraviolet high-brightness LEDs
  • Aluminum gallium indium phosphide (AlGaInP): yellow, orange and red high-brightness LEDs
  • Aluminum gallium arsenide (AlGaAs): red and infrared LEDs
  • Gallium phosphide (GaP): yellow and green LEDs

How white light is produced?

There are several methods of generating white light using LEDs. Below is 2 typical emission methods.

Blue LED+Yellow Phosphor

Combining a blue LED with yellow phosphor is a widely used method to produce white light. The blue LED emits light in the blue spectrum that passes through a layer of yellow phosphor, which is a material that absorbs some of the blue light and re-emits it as yellow light. The combination of the remaining blue light and the newly emitted yellow light creates white light. This is because blue and yellow are complementary colors, and when mixed, they produce a broad spectrum of light that appears white to the human eye.This method is easier than other solutions and provides high efficiency, making it the most popular choice on the market. 

Blue LED + Yellow Phosphor

Red LED+Green LED+Blue LED

Combining red, green, and blue LEDs can produce white light through a process called additive color mixing. When the light from these three primary colors is combined in the right proportions, it creates the perception of white light. This method is commonly used in full-color LED devices, such as screens and displays, to produce a wide range of colors by varying the intensity of each LED

Red LED + Green LED + Blue LED

 

General Considerations For LED Encapsulants

As LED encaplants, besides general consideration of packaging materials, optical performance with long-term reliability is specially emphasized. 

generalconsiderationsforLEDenacapsulation

Challenges & Solutions

Challenges Problem Description Encapsulation Solutions
Light Extraction
  • Refractive index mismatch between LED die (~1.58) and encapsulants, affecting energy output efficiency 
  • High RI (refractive index) encapsulant 
Delamination
  • Stress failure caused by CTE mismatch among encapsulant, die and lead frame during curing or temperature shifting;
  • Moisture absorption and ions corrosion
  • Adhesion issue 
  • Matched CTE and low modulus materials
  • Excellent adhesion to substrate
  • Moisture resistance material with high purity
Thermal-Yellowing
  • Thermal degradation and discoloration induced by high junction temperature between die and leadframe 
  • High Tg epoxy encapsulant with high cross-link and strong INP
  • Add anti-yellowing agents
  • Silicone based encapsulants
UV-Yellowing
  • Photo degradation induced by UV radiation from LED die and outdoor UV
  • UV transparent encapsulant
  • Silicone based encapsulants
Aging/Lifetime
  • Aging caused by thermal and UV degradation
  • Aging will result in mechanical failure, transmission decay and discoloration
Above All
Sensor Transmission
  • High transmission within application wavelength to avoid disturbing signals
  • Add dyes as cut-off or bandpass filter

 

LED Clear Molding Compounds Product Overview 

 

Monochrome LEDs

HD RGB LEDs 

White LEDs

Product

TC-8020

(Star Product)

TC-8040

TC-7600

(Popular Product)

TC-7800

(In Development)

TC-8030

TC-8060

(Popular Product)

TC-8090

(In Development)

Summary

  • Good adhesion to BT substrate/metal leadframe 
  • Adequate flexural modulus/strength 
  • Excellent anti-reflow performance. 
  • Good processability and moldability
  • Great moisture resistance property
  • Enable LED display pass hash durability tests 
  • Ensures uniform colours and uniform emitting light at large angles
  • Reduce warpage
  • Excellent anti-yellowish performance at high temperature
  • Reduced light decline by blue/white light
  • Excellent adhesion to Ag/Cu and PCB substrate 
  • Good moldability and higher reliability
  • Two optional forms: cylindrical tablets, and fine powder

Applications

7-segment LED display, compact LED indicator, monochrome Chip LED, photo-link

High density (fine-pitch) RGB LED display

Decorative White LED

Backlight

High Reliability 

Backlight

Light Decline

Aging Test

-

Medium

10-50%

RT*20mA*500hrs

Medium

10-50%

RT*5mA*1000hrs

Low

<50%

RT*20mA*500hrs

High

<10%

RT*5mA*1000hrs

Reliability Tests

Reflow, TCT, 85℃@85%RH

Reflow, TCT, 85℃@85%RH, PCT

Reflow, TCT, 85℃@85%RH

Highlight

Low stress and filter versions available

High reliability

Mid blue-ray decay

Low blue-ray decay 

Low blue-ray decay 

High anti-yellowish

Low cost

Low blue-ray decay

Low blue-ray decay

Anti-moisture

Comparable

 XX-18, XX-1012, XX-8524

XX-600H

XX-600H

XX-600H-94000

XX-1014, XX-8524

XX-1000, XX-814, XX-97

XX-1000, XX-814, XX-97

Child Product

TC-8020L/LS low-stress

TC-8020T-SR self-release version

TC-8050 for large package

 

 

 

TC-8034 with low decay

TC-8036 with low decay

Low CTE product TC-9000T with transparent filler

TC-8060 IMP low modulus version

 



Die Attach For LEDs

LOCTITE ABLESTIK ABP 8037TI silver-filled die attach adhesive paste is specifically designed to attach small diodes in high volume manufacturing. Even more specifically, it is the highest volume silver-filled die attach paste for high reliability LED attach and manufacture when using small die on Au-finished leadframes. Used in high-volume manufacturing throughout China and Malaysia.

Also extremely popular:

LOCTITE ABLESTIK 84-1LMISR4 is a manufacturer's product of choice, can be used for LED applications and like most epoxies it is suitable for Copper substrates.

One alternative:

LOCTITE® ABLESTIK ABP 8035M is a non-conductive clear silicone designed for high brightness LED die attach applications.

Non conductive option:

LOCTITE ABLESTIK QMI536NB creates packages and devices that have high resistance to delamination and popcorning after multiple exposures to lead-free solder reflow temperatures. It has good optical performance with high transmittance, Optical Density and HRI and is  a great solution for ASIC attach and LED attach.

 

Frequently Asked Questions about Light Emitting Diodes

What is the difference between OLED and AMOLED?

OLED (Organic Light Emitting Diode) displays use organic materials to emit light when an electric current is applied, allowing each pixel to emit its own light for deep blacks and high contrast. However, they use a passive matrix to control pixels, which is slower and less precise, making them suitable for smaller screens.

In contrast, AMOLED (Active Matrix Organic Light Emitting Diode) displays incorporate an active matrix layer with thin-film transistors (TFTs) and capacitors for faster pixel response times, higher refresh rates, and more precise control. This makes AMOLED displays ideal for larger screens and higher resolutions, offering better performance and efficiency, which is why they are commonly used in high-end smartphones and tablets.

How does the encapsulation material affects the performance of LEDs?

The materials used in LED encapsulants significantly impact their performance by providing protection and enhancing efficiency. Encapsulants shield the delicate LED chip from environmental factors such as moisture, dust, and UV radiation, which can degrade performance over time. Materials like epoxy resins offer excellent adhesion, thermal resistance, and light transmission, ensuring consistent light output and durability. Silicone encapsulants provide superior thermal stability and UV resistance, making them ideal for harsh conditions. Polyurethane and acrylic encapsulants offer mechanical strength and optical clarity, respectively. By selecting the appropriate encapsulant material, manufacturers can enhance the longevity, efficiency, and overall performance of LEDs.

What is the diffrence between color filtering and color conversion?

Color filtering involves selectively allowing certain wavelengths of light to pass through while blocking others. This process does not change the wavelength of the light; it simply filters out unwanted colors. For example, a red filter will let red light pass through while absorbing or reflecting other colors.

Color conversion, on the other hand, involves changing the wavelength of light. This process absorbs light at one wavelength and re-emits it at a different wavelength. For instance, a material might absorb blue light and re-emit it as green light. This is commonly used in applications like phosphor coatings in LEDs, where blue light is converted to white light by re-emitting it at different wavelength. 

 

What is the difference between SMT and Through-hole LEDs?

The primary difference between SMT (Surface-Mount Technology) and through-hole LEDs lies in their mounting methods and applications. SMT LEDs are mounted directly onto the surface of a printed circuit board (PCB) without the need for drilling holes. This allows for a more compact design, higher component density, and automated assembly, making them ideal for modern, space-constrained electronic devices. In contrast, through-hole LEDs have leads that pass through holes drilled in the PCB and are soldered on the opposite side. This method provides greater mechanical stability and is often used in applications requiring durability and resistance to physical stress, such as industrial equipment and outdoor displays. 

Presentations

Materials for Optoelectronic Application

 

Silicones for LED Packages

Phosphor in Silcone Films for CSP LED

Liquid Encapsualnt for LEDs